Noninvasive Solution for Electrochemical Impedance Spectroscopy on Metallic Works of Art

Metallic works of art of cultural relevance are continuously subjected to corrosion as the environment becomes increasingly polluted. A fast and simple method to in situ assess the conservation conditions is therefore required. This paper describes the development and performance of dry and gel-based electrodes which can be used to assess the surface conservation state without the need to move the artifacts and which do not cause any damage to them. The electrodes can be used with a portable electrochemical impedance spectroscopy system, without employing electrochemical cells. The proposed solution does not provide all the information that one can obtain using an electrochemical cell, but it can discriminate between protective coatings. It can be used to assess the protective capability of corrosion product layers and natural patinas, and it can therefore enable a noninvasive routine surface assessment to be conducted that could be extremely useful for people working in the field of conservation of cultural heritag

A Remotely Controlled Calibrator for Chemical Pollutant Measuring-Units

The increasing diffusion of pollutant measuring units, which are installed over wide areas, along with the short calibration interval of several sensors for pollutant quantities, requires new calibration infrastructures to be developed. This paper describes an attempt to develop an innovative calibration system which is based on traveling standards and which does not require units to be removed from the measuring site during the calibration process. The calibration system is based on a traveling standard, which is composed of one or more cylinders that contain gas mixtures, a cell with standard sensors, and a control unit with networking capabilities, which allows the traveling standard to be remotely exercised. A prototype of the proposed system is described and the preliminary results reporte

Low-Cost Laser-Based Localization System for Agricultural Machines

This paper describes the design and test of a low-cost localization system for agricultural applications, which determines a tractor position in fields up to 0.5 km with an uncertainty of about 1 m. The proposed system employs a standard unmodified laser head, which is commonly used for field leveling, plus a reference ground-fixed laser receiver and requires neither laser modulation nor expensive time-of-flight measurements of light beam

Microwave Measurements. Part II - Nonlinear Measurements

This paper addresses the problems in microwave non-linear measurements. It discusses techniques to synthesize loads, the most used non-linear measurement techniques, and harmonic load-pulling. An experimental setup for characterizing power amplifiers must be able to measure the complex spectrum of the waves at the amplifier ports as a function of frequency, input power, and source and load termination at the fundamental and harmonic frequencies. The vector network analyzer (VNA) is the core instrument used in the non-linear characterization scenario. The basic idea is to keep the operations of VNA/mixers linear, diverting to them only a small portion of the signal present at the device under test (DUT) ports, therefore keeping unaltered the VNA capabilities already exhibited for small signal measurements

A Wireless Sensor Network for Cold-Chain Monitoring

This paper deals with a wireless sensor network that was specifically designed to monitor temperature-sensitive products during their distribution with the aim of conforming to the cold-chain assurance requirements. The measurement problems and the constraints that have been encountered in this application are initially highlighted, and then, an architecture that takes such problems into account is proposed. The proposed architecture is based on specifically designed measuring nodes that are inserted into the products to identify their behavior under real operating conditions, e.g., during a typical distribution. Such product nodes communicate through a wireless channel with a base station, which collects and processes the data sent by all the nodes. A peculiarity of the product nodes is the low cost, which allows the information on the cold-chain integrity to be provided to the final customer. The results that refer to the functional tests of the proposed system and to the experimental tests performed on a refrigerated vehicle during a distribution are reporte

In Situ Calibration of Heterogeneous Acquisition Systems: The Monitoring System of a Photovoltaic Plant

This paper deals with the metrological management of an acquisition system that has been developed for monitoring an experimental photovoltaic (PV) plant. The acquisition system has been conceived for comparing the performance of different PV technologies and for verifying the nominal specifications of the PV modules. For these reasons, the traceability of the monitoring system has to be ensured, and therefore, it must be periodically calibrated. A remotely exercised procedure is proposed for the calibration of the acquisition system, which is based on a calibrator specifically designed for this application. This calibrator has the capability to act as a reference for heterogeneous quantities, including electrical quantities, temperature, and solar irradiance. The architecture of this calibrator is described, and experimental results for the preliminary characterization of the prototype are described

Accurate Characterization of High-Q Microwave Resonances for Metrology Applications

Microwave resonators are widely adopted as high sensitivity sensors in both applied and fundamental metrology, to measure a number of different physical quantities, such as temperature, humidity, pressure, length and material properties. High sensitivity, and thus potential high measurement precision and accuracy, can be achieved by resorting to high-quality-factor ( $Q$ ) resonators. Nonetheless, in order to accurately measure a high- $Q$ resonance and obtain low measurement uncertainty, as required by metrology applications, the entire measurement set-up must be carefully designed. This papers presents an overview of resonance frequency measurements for metrology applications, illustrating the various aspects and issues to be dealt with when pursuing highly accurate measurements, as well as of the most relevant achievements in this field

Modified POF Sensor for Gaseous Hydrogen Fluoride Monitoring in the Presence of Ionizing Radiations

This paper describes the development of a sensor designed to detect low concentrations of hydrogen fluoride (HF) in gas mixtures. The sensor employs a plastic optical fiber (POF) covered with a thin layer of glass- like material. HF attacks the glass and alters the fiber transmission capability so that the detection simply requires a LED and a photodiode. The coated POF is obtained by means of low-pressure plasma-enhanced chemical vapor deposition that allows the glass-like film to be deposited at low temperature without damaging the fiber core. The developed sensor will be installed in the recirculation gas system of the resistive plate chamber muon detector of the Compact Muon Solenoid experiment at the Large Hadron Collider accelerator of the European Organization for Nuclear Research (CERN

Exposure-Tolerant Imaging Solution forCultural Heritage Monitoring

This paper describes a simple and cheap solution specifically designed for monitoring the degradation of thin coatings employed for metal protection. The proposed solution employs a commercial photocamera and a frequency-domain-based approach that is capable of highlighting the surface uniformity changes due to initial corrosion. Even though the proposed solution is specifically designed to monitor the long-time performance of protective coatings employed for the restoration of silver artifacts, it can be successfully used also for assessing the conservation state of other ancient metallic works of art. The proposed solution is made tolerant to exposure changes by using a procedure for sensor nonlinearity identification and correction, does not require a precise lighting control, and employs only free open-source software, so that its overall cost is very low and can be used also by not specifically trained operator

Discriminating Pathological Voice From Healthy Voice Using Cepstral Peak Prominence Smoothed Distribution in Sustained Vowel

This paper deals with cepstral peak prominence smoothed (CPPS) distribution and its descriptive statistics as possible indicators of vocal health status. A total of 41 voluntary patients and 35 control subjects participated in the experiment: all of them followed the same protocol, which includes three repetitions of the sustained vowel /a/ simultaneously acquired with a microphone in air and a contact sensor, the perceptual assessment of voice quality, and the videolaringoscopy examination. The fifth percentile and the standard deviation of CPPS distribution were the parameters included in the best logistic regression models for the microphone in air and the contact sensor, respectively. The selected CPPS parameters had a strong to good discrimination power: an area under curve of 0.95 and 0.87 has been found for the microphone in air and for the contact sensor, respectively. For each CPPS parameter, the repeatability has been also estimated and the Monte Carlo method has been implemented for the uncertainty evaluation of the discrimination threshold. Furthermore, preliminary recommendations for better accuracy and repeatability of future studies are provided: analyses on the main CPPS influence quantities and on the effect of the frequency content of the signal spectrum on the CPPS parameters have been provided